| HRAC Group |
Site of Action |
Chemical Family |
Active Ingredient |
WSSA Group |
|
A
|
Inhibition of acetyl
CoA carboxylase
(ACCase) |
Aryloxyphenoxy-propionate
‘FOPs’
|
clodinafop-propargyl
cyhalofop-butyl
diclofop-methyl
fenoxaprop-P-ethyl
fluazifop-P-butyl
haloxyfop-R-methyl
propaquizafop
quizalofop-P-ethyl |
1
|
| |
|
Cyclohexanedione
‘DIMs’ |
alloxydim
butroxydim
clethodim
cycloxydim
profoxydim
sethoxydim
tepraloxydin
tralkoxydim |
|
| |
|
Phenylpyrazoline
‘DEN’ |
pinoxaden |
|
|
B
|
Inhibition of acetolactate synthase ALS
(acetohydroxyacid synthase AHAS) |
Sulfonylurea |
amidosulfuron
azimsulfuron
bensulfuron-methyl
chlorimuron-ethyl
chlorsulfuron
cinosulfuron
cyclosulfamuron
ethametsulfuron-methyl
ethoxysulfuron
flazasulfuron
flupyrsulfuron-methyl-Na
foramsulfuron
halosulfuron-methyl
imazosulfuron
iodosulfuron
mesosulfuron
metsulfuron-methyl
nicosulfuron
oxasulfuron
primisulfuron-methyl
prosulfuron
pyrazosulfuron-ethyl
rimsulfuron
sulfometuron-methyl
sulfosulfuron
thifensulfuron-methyl
triasulfuron
tribenuron-methyl
trifloxysulfuron
triflusulfuron-methyl
tritosulfuron |
2
|
| |
|
Imidazolinone |
imazapic
imazamethabenz-methyl
imazamox
imazapyr
imazaquin
imazethapyr |
|
| |
|
Triazolopyrimidine |
cloransulam-methyl
diclosulam
florasulam
flumetsulam
metosulam
penoxsulam |
|
| |
|
Pyrimidinyl(thio)benzoate |
bispyribac-Na
pyribenzoxim
pyriftalid
pyrithiobac-Na
pyriminobac-methyl |
|
| |
|
Sulfonylaminocarbonyl-triazolinone |
flucarbazone-Na
propoxycarbazone-Na |
|
| HRAC Group |
Site of Action |
Chemical Family |
Active Ingredient |
WSSA Group |
|
C1
|
Inhibition of photosynthesis at
photosystem II |
Triazine |
ametryne
atrazine
cyanazine
desmetryne
dimethametryne
prometon
prometryne
propazine
simazine
simetryne
terbumeton
terbuthylazine
terbutryne
trietazine |
5
|
| |
|
Triazinone |
hexazinone
metamitron
metribuzin |
|
| |
|
Triazolinone |
amicarbazone |
|
| |
|
Uracil |
bromacil
lenacil
terbacil |
|
| |
|
Pyridazinone |
pyrazon = chloridazon |
|
| |
|
Phenyl-carbamate |
desmedipham
phenmedipham |
|
|
C2
|
Inhibition of photosynthesis at
photosystem II |
Urea |
chlorobromuron
chlorotoluron
chloroxuron
dimefuron
diuron
ethidimuron
fenuron
fluometuron (see F3)
isoproturon
isouron
linuron
methabenzthiazuron
metobromuron
metoxuron
monolinuron
neburon
siduron
tebuthiuron |
7
|
| |
|
Amide |
propanil
pentanochlor |
|
|
C3
|
Inhibition of photosynthesis at
photosystem II |
Nitrile |
bromofenoxim
bromoxynil
ioxynil |
6
|
| |
|
Benzothiadiazinone |
bentazon |
|
| |
|
Phenyl-pyridazine |
pyridate
pyridafol |
|
|
D
|
Photosystem-I-electron diversion |
Bipyridylium |
diquat
paraquat |
22
|
| HRAC Group |
Site of Action |
Chemical Family |
Active Ingredient |
WSSA Group |
|
E
|
Inhibition of protoporphyrinogen oxidase
(PPO) |
Diphenylether |
acifluorfen-Na
bifenox
chlomethoxyfen
fluoroglycofen-ethyl
fomesafen
halosafen
lactofen
oxyfluorfen |
14
|
| |
|
Phenylpyrazole |
fluazolate
pyraflufen-ethyl |
|
| |
|
N-phenylphthalimide |
cinidon-ethyl
flumioxazin
flumiclorac-pentyl |
|
| |
|
Thiadiazole |
fluthiacet-methyl
thidiazimin |
|
| |
|
Oxadiazole |
oxadiazon
oxadiargyl |
|
| |
|
Triazolinone |
azafenidin
carfentrazone-ethyl
sulfentrazone |
|
| |
|
Oxazolidinedione |
pentoxazone |
|
| |
|
Pyrimidindione |
benzfendizone
butafenacil |
|
| |
|
Other |
pyraclonil
profluazol
flufenpyr-ethyl |
|
|
F1
|
Bleaching:
Inhibition of carotenoid biosynthesis at the phytoene desaturase step (PDS) |
Pyridazinone |
norflurazon |
12
|
| |
|
Pyridinecarboxamide |
diflufenican
picolinafen |
|
| |
|
Other |
beflubutamid
fluridone
flurochloridone
flurtamone |
|
|
F2
|
Bleaching:
Inhibition of 4-hydroxyphenyl-pyruvate-dioxygenase (4-HPPD) |
Triketone |
mesotrione
sulcotrione |
27
|
| |
|
Isoxazole |
isoxachlortole
isoxaflutole |
|
| |
|
Pyrazole |
benzofenap
pyrazolynate
pyrazoxyfen |
|
| |
|
Other |
benzobicyclon |
|
|
F3
|
Bleaching:
Inhibition of carotenoid biosynthesis (unknown target) |
Triazole |
amitrole
(in vivo inhibition of
lycopene cyclase) |
11
|
| |
|
Isoxazolidinone |
clomazone |
13
|
| |
|
Urea |
fluometuron (see C2) |
|
| |
|
Diphenylether |
aclonifen |
|
|
G
|
Inhibition of EPSP synthase |
Glycine |
glyphosate
sulfosate |
9
|
|
H
|
Inhibition of glutamine synthetase |
Phosphinic acid |
glufosinate-ammonium
bialaphos = bilanaphos |
10
|
| HRAC Group |
Site of Action |
Chemical Family |
Active Ingredient |
WSSA Group |
|
I
|
Inhibition of DHP (dihydropteroate) synthase |
Carbamate |
asulam |
18
|
|
K1
|
Microtubule assembly inhibition |
Dinitroaniline |
benefin = benfluralin
butralin
dinitramine
ethalfluralin
oryzalin
pendimethalin
trifluralin |
3
|
| |
|
Phosphoroamidate |
amiprophos-methyl
butamiphos |
|
| |
|
Pyridine |
dithiopyr
thiazopyr |
|
| |
|
Benzamide |
propyzamide = pronamide
tebutam |
|
| |
|
Benzoic acid |
DCPA = chlorthal-dimethyl |
3
|
|
K2
|
Inhibition of mitosis / microtubule organisation |
Carbamate |
chlorpropham
propham
carbetamide |
23
|
|
K3
|
Inhibition of VLCFAs ( see Remarks)
(Inhibition of cell division) |
Chloroacetamide |
acetochlor
alachlor
butachlor |
15
|
| |
|
|
dimethachlor
dimethanamid
metazachlor
metolachlor
pethoxamid |
|
| |
|
|
pretilachlor
propachlor
propisochlor
thenylchlor |
|
| |
|
Acetamide |
diphenamid
napropamide
naproanilide |
|
| |
|
Oxyacetamide |
flufenacet
mefenacet |
|
| |
|
Tetrazolinone |
fentrazamide |
|
| |
|
Other |
anilofos
cafenstrole
piperophos |
|
|
L
|
Inhibition of cell wall (cellulose) synthesis |
Nitrile |
dichlobenil
chlorthiamid |
20
|
| |
|
Benzamide |
isoxaben |
21
|
| |
|
Triazolocarboxamide |
flupoxam |
|
| |
|
Quinoline carboxylic acid |
quinclorac (for monocots)
(also group O) |
26
|
| HRAC Group |
Site of Action |
Chemical Family |
Active Ingredient |
WSSA Group |
|
M
|
Uncoupling (Membrane disruption) |
Dinitrophenol |
DNOC
dinoseb
dinoterb |
24
|
|
N
|
Inhibition of lipid synthesis - not ACCase inhibition |
Thiocarbamate |
butylate
cycloate
dimepiperate
EPTC
esprocarb
molinate
orbencarb
pebulate
prosulfocarb
thiobencarb = benthiocarb
tiocarbazil
triallate
vernolate |
8
|
| |
|
Phosphorodithioate |
bensulide |
|
| |
|
Benzofuran |
benfuresate
ethofumesate |
|
| |
|
Chloro-Carbonic-acid |
TCA
dalapon
flupropanate |
26
|
|
O
|
Action like indole acetic acid
(synthetic auxins) |
Phenoxy-carboxylic-acid |
clomeprop
2,4-D
2,4-DB
dichlorprop = 2,4-DP
MCPA
MCPB
mecoprop = MCPP = CMPP |
4
|
| |
|
Benzoic acid |
chloramben
dicamba
TBA |
|
| |
|
Pyridine carboxylic acid |
clopyralid
fluroxypyr
picloram
triclopyr |
|
| |
|
Quinoline carboxylic acid |
quinclorac
(also group L)
quinmerac |
|
| |
|
Other |
benazolin-ethyl |
|
|
P
|
Inhibition of auxin transport |
Phthalamate
Semicarbazone |
naptalam
diflufenzopyr-Na |
19
|
| HRAC Group |
Site of Action |
Chemical Family |
Active Ingredient |
WSSA Group |
|
R
|
.... |
... |
... |
|
|
S
|
... |
... |
... |
|
|
.
|
... |
... |
... |
|
|
Z
|
Unknown
Note: While the site of action of herbicides in Group Z is unknown it is likely that they differ in site of action between themselves and from other groups. |
Arylaminopropionic acid |
Flamprop-M-methyl /-isopropyl |
25
|
| |
|
Pyrazolium |
difenzoquat |
26
|
| |
|
Organoarsenical |
DSMA
MSMA |
17
|
| |
|
Other |
bromobutide
(chloro)-flurenol |
|
| |
|
|
cinmethylin |
|
| |
|
|
cumyluron |
|
| |
|
|
dazomet |
|
| |
|
|
dymron = daimuron
methyl-dimuron=
methyl-dymron
etobenzanid
fosamine
indanofan
metam
oxaziclomefone
oleic acid |
|
| |
|
|
pelargonic acid
pyributicarb |
|